Extraction of Niobium from ore deposits in KPK, Pakistan

Authors

  • Muhammad Irfan
  • Muhammad Imran Ahmad
  • Muhammad Saleem Khan

DOI:

https://doi.org/10.24949/njes.v7i1.40

Abstract

The extraction of Niobium through different extraction processes is reviewed in this paper. On the commercial scale the solvent extractants have been employed for the extraction of Niobium in the presence of hydrogen fluoride. But the emission of HF enhances the environmental impacts. In HF processes a proper disposal area is required for the production of huge amount of fluorspar sludge as a by-product and a special treatment method is required in order to reduce the environmental impacts. Alkali potash has been used for Niobium extraction in the absence of HF. In this paper different processes of Niobium extraction are reviewed and a suitable process is selected for application in Pakistan. The Niobium extraction processes are classified as direct leaching processes and hydrometallurgical processes. Different solvents which are used for extraction of Niobium in hydrometallurgical processes are compared and their properties evaluated. 

References

G. L. Miller, “Metallurgy of the Rarer Metals-6: Tantalum and Niobium”, Isaac Pitman & Sons LTD, 1957.

A. I. Nikolaev, and V. G. Maiorov, “New approaches to Niobium and tantalum extraction technology”, Doklady Chemistry, Vol. 415, No. 1, 2007, pp. 167-169.

S. N. Bhattacharyya, and B. Ganguly, “Solvent extraction separation of Niobium and tantalum”, Solvent Extraction and Ion Exchange, Vol. 2, 1984, pp. 699-740.

C. Y Cheng Zhu, “Solvent extraction technology for the separation and purification of Niobium and tantalum: review”, Hydrometallurgy, 1984, Vol. 107, 2011, pp. 1-12.

D. Blauwet, Minerals, Mountains and Majesty, Lithographie, LLC, 2004, pp. 96.

A. H. Kazmi, and S. G. Abbasi, “Metallogeny and mineral deposits of Pakistan”, Graphic publishers, Karachi, 2001, pp. 264.

Hongming Zhou, Shili Zheng and Yi Zhang, “Leaching of a low-grade Niobium–tantalum ore by highly concentrated caustic potash solution”, Hydrometallurgy, Vol. 80, 2005, pp. 83-89.

El-Hussaini and Mahdy, “Sulfuric acid leaching of Kab Amiri Niobium–tantalum bearing minerals Central Eastern Desert, Egypt”, Hydrometallurgy, Vol. 64, 2002, pp. 219–229.

Htet Htwe, and Kay Thi Lwin, “Study on Extraction of Niobium Oxide from Columbite–Tantalite Concentrate”, World Academy of Science, Engineering and Technology, Vol. 46, 2008.

O. M. EL Hussaini, “Extraction of Niobium from sulfate leach liquor of Egyptian ore sample by triazoloquinazolinone”, Trans Nonferrous Met. Soc.China, Vol. 19, 2009, pp. 474-478.

M. N. El-Hazek, T. E Amer, and R. M. Issa, “Liquid–liquid extraction of tantalum and Niobium by octanol from sulfate leach liquor”, Arabian Journal of Chemistry, 2011.

J. Han, and Y. Zhou, “Development of Ta & Nb extraction and stripping technology and equipment”, Rare Metals and Cemented Carbides, Vol. 32, No.2, 2004, pp. 15-20.

V. G. Maiorov, and A. I. Nikolaev, “Tantalum (V) and Niobium (V) extraction by octanol”, Hydrometallurgy, Vol. 66, 2002, pp. 77-83.

C. K. Gupta, and A. K. Suri, “Niobium and Tantalum Separation Process”, Extractive Metallurgy of Niobium, CRC. Press Inc, Boca Raton, Florida, 1994, pp. 125-127.

W. L. Hunter, “Separation of tantalum and columbium by liquid–liquid extraction”, Transactions of the Metallurgical Society of AIME, Vol. 245, 1969, pp. 1999-2007.

T. Okada, “Manufacturing of Special Niobium Oxides for Optical and Ceramic Applications”, International Symposium on Niobium. December, Orland, FL, USA, December 2001.

S. Nishimura, J. Moriyama, and I. Kushima, “Extraction and separation of tantalum and Niobium by liquid–liquid extraction in the HF–H2SO4–TBP system”, Transactions of the Japan Institute of Metals, Vol. 5, 1964, pp. 39–42.

S. Nishimura, J. Moriyama and, I. Kushima, “Extraction and separation of tantalum and Niobium by liquid–liquid extraction in the hydrofluoric acid– tributyl phosphate system”, Transactions of the Japan Institute of Metals, 1963, pp. 4259-4262.

J. Xie, “A study on the mechanism of extraction of tantalum and Niobium with MIBK in

HF–H2SO4 system”, Rare Metals (in Chinese), Vol. 7, No. 3, 1988, pp. 213-214.

J. Eckert, “Hydrometallurgical Processing of Tantalum and Niobium”, Proceedings of International Symposium on Tantalum and Niobium, TIC, Brussels, Goslar, Germany, September 52-64, 1995.

S. A. Markland, “Separation of Niobium and Tantalum by Solvent Extraction with Tertiary Amines from Sulfuric acid Solutions”, In: Jeffreys, G.V. (Ed.), Proceedings of the International Solvent Extraction Conference 1974, 3. Society of Chemical Industry, London, Lyon, France, 2185-2196, 1974.

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Published

2015-06-15

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Engineering Sciences