High Temperature Effectiveness of Ginger Extract as Green Inhibitor for Corrosion in Mild Steel

Authors

  • Muhammad Sohail NED University of Engineering and Technology
  • Fayaz Hussain
  • Ali Dad Chandio NED University of Engineering and Technology
  • Maryam Sheikh NED University of Engineering and Technology

DOI:

https://doi.org/10.24949/njes.v11i1.266

Keywords:

Mild Steel, Green Corrosion Inhibitor, Ginger extract, linear polarization

Abstract

Corrosion is one of the major problems of mild steels in acidic medium. This can be minimized by the application of corrosion inhibitors, however; the most of inhibitors are toxic in nature. Therefore inhibitors from green sources are highly desirable to maintain the sustainability of the environmental system. Consequently, in this study ginger was selected; its juice extracted mechanically and used as an inhibitor. The different concentrations of ginger extract such as 0.25ml, 0.5ml, 0.75ml and 1ml were mixed in 0.1 M HCl solution to record the effect of inhibitor on corrosion rate at room temperature and at an elevated temperature of 50ᵒC. Electrochemical linear polarization resistance (LPR) tests were carried out to determine the corrosion rates at both temperatures with different additions of the inhibitor respectively. The LPR test uses three electrodes, first electrode of AISI 1019 (mild steel), second electrode is standard electrode of saturated calomel while the third electrode consists of graphite, which is called counter electrode, to measure potential difference. The whole assembly was dipped in the solution having varying concentration of inhibitors. The corrosion rate was found to be higher in the absence of ginger- extract. Conversely, the corrosion rate was dramatically reduced more prominently at 50oC but was less effective at Troom; with the trace-additions of ginger-inhibitor. So this research would be the good contribution to overcome the deterioration of mild steel and increase its life at ambient temperatures, by using economically available environmentally-friendly organic compound specially the use of locally available raw material should be focused.

Author Biographies

Muhammad Sohail, NED University of Engineering and Technology

Department of Materials Engineering, Assistant Professor

Ali Dad Chandio, NED University of Engineering and Technology

Dr. Ali Dad Chandio is currently working in Department of Materials Engineering as Assistant Professor. He got his Ph. D. from The University of Manchester, UK in Dec 2015

Maryam Sheikh, NED University of Engineering and Technology

Ms. Maryam Sheikh is studying as a Master's Student in Department of Materials Engineering.

References

Bouyanzer, A. and B. Hammouti, A study of anti-corrosive effects of Artemisia oil on steel. Pigment & resin technology, 2004. 33(5): p. 287-292.

Oguzie, E.E., Evaluation of the inhibitive effect of some plant extracts on the acid corrosion of mild steel. Corrosion Science, 2008. 50(11): p. 2993-2998.

Africa, S., Adsorption and inhibitive properties of ethanol extracts of Musa sapientum peels as a green corrosion inhibitor for mild steel in H2SO4. African Journal of Pure and Applied Chemistry, 2008. 2(6): p. 046-054.

Arab, S.T., A.M. AL-TURKUSTANI, and S.Y. AI-Nami, UTILIZATION OF AMMIMAJUS L. FRUITS EXTRACTS AS INHIBITORS FOR MILD STEEL CORROSION IN ACID MEDIA. Science, 2005. 3(2).

Oguzie, E.E., Studies on the inhibitive effect of Occimum viridis extract on the acid corrosion of mild steel. Materials Chemistry and Physics, 2006. 99(2): p. 441-446.

Ashassi-Sorkhabi, H. and D. Seifzadeh, The inhibition of steel corrosion in hydrochloric acid solution by juice of Prunus cerasus. Int. J. Electrochem. Sci, 2006. 1(1): p. 92-6.

Bouyanzer, A., B. Hammouti, and L. Majidi, Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1M HCl. Materials Letters, 2006. 60(23): p. 2840-2843.

Eddy, N., Ebenso (2008). Adsorption and inhibitive properties of ethanol extracts of Musa sapientum peels as a green corrosion inhibitor for mild steel in H2SO4, African J. Pure Appl. Chem. 2(6): p. 046-054.

Singh, A., E.E. Ebenso, and M. Quraishi, Corrosion Inhibition of carbon steel in HCl solution by some plant extracts. International Journal of corrosion, 2012. 2012.

Qureshi, H.M., et al., Evaluation of antihistaminic and anticholinergic activities of Murraya koenigii Linn. Pak Vet J, 2015. 35: p. 242-44.

Singh, A., V. Singh, and M. Quraishi, Effect of fruit extracts of some environmentally benign green corrosion inhibitors on corrosion of mild steel in hydrochloric acid solution. Journal of Materials and Environmental Science, 2010. 1(3): p. 162-174.

Quraishi, M., et al., Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid solutions by the extract of Murraya koenigii leaves. Materials chemistry and Physics, 2010. 122(1): p. 114-122.

Noor, E.A., Comparative study on the corrosion inhibition of mild steel by aqueous extract of Fenugreek seeds and leaves in acidic solution. Journal of Engineering and Applied Sciences, 2008. 3(1): p. 23-30.

Dekmouche, M., et al., Green Approach to Corrosion Inhibition by Ethyl acetate Extract from Pistacia atlantica Gals in Hydrochloric Acid Solution. Int. J. Electrochem. Sci, 2014. 9: p. 3969-3978.

Khan, G., et al., Application of natural product extracts as green corrosion inhibitors for metals and alloys in acid pickling processes-a review. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2015. 10(8): p. 6120-6134.

Ghareba, S. and S. Omanovic, Interaction of 12-aminododecanoic acid with a carbon steel surface: towards the development of ‘green’corrosion inhibitors. Corrosion Science, 2010. 52(6): p. 2104-2113.

Sastri, V.S., Corrosion Inhibition Mechanisms, in Green Corrosion Inhibitors. 2011, John Wiley & Sons, Inc. p. 167-211.

Gomaa, M.M.B.E.S.H.F.Y.K.M.H.M.B.N.A.M.A.Z., Aqueous Extract of Ginger as Green Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution. International Journal of Scientific & Engineering Research, 2015. 6 (6): p. 7.

Tao, Y., et al., Identification and quantification of gingerols and related compounds in ginger dietary supplements using high-performance liquid chromatography-tandem mass spectrometry. J Agric Food Chem, 2009. 57(21): p. 10014-21.

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Published

2019-03-10

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Section

Engineering Sciences